This post from Ed Harris on Handloads.com explains better than I.
"The usual .357 Magnum rifle chamber resembles the same form used in the SAAMI pressure test barrel. That is simply a 15-degree included angle forcing cone which departs directly from the cylindrical .379 diameter at the case mouth, with no "ball seat."
Testing was published by the NRA in the 1980s in which T/C Contender handguns and Marlin 1894 rifles were rethroated, using a more gradual 3 degree forcing cone. This reamer followed the form of automatic match pistols produced by the US Army Marksmanship Unit (AMU) which were chambered for .38 Special wadcutter ammunition. The ".38 AMU style" chamber throat put on a .357 Magnum-length reamer improved accuracy dramatically, reducing long run average group size by 25-50%.
You can buy the ".357 NRA" chambering reamer with this throating from JGS Guntools. It is a custom design which is made to order and cost is about $165 last time I checked. It is easy to re-cut the chamber throat of .357 Magnum rifles by hand to correct "problem" shooters."