Casting with zinc requires pressure or a centrifuge, and often requires keeping sprues molten until the mold cools. Recent advancements include a "High-Fluidity" zamak, which has a lower amount of aluminum (what makes zamak lighter than zinc) but a high amount of copper with small amounts of iron and other goodies. I'm saving my berdan brass for this... and all the pop cans I keep instead of recycle. Those cans are mostly (>92%) aluminum but something like 3-5% magnesium, also. Spent primers I save for this as well.
What's important is how the alloy behaves at velocity, and this HF stuff could become a game changer.