Hi guys.
Seems to me that it might be feasible to boil zinc out of lead or other alloys (such as zinc bearing pewter).
Boiling points:
Tin 2,603° C (4,717° F)
Copper 2,567° C (4,652° F)
Lead 1,750° C (3,182° F)
Antimony 1,587° C (2,888° F)
Zinc 906.8° C (1,664° F)
Of course I'm assuming that alloys retain the boiling points of their constituent parts. There's surprising little information about boiling points and alloys that I could find on the web.
What I'm thinking of as a test would be to deliberately create a batch of lead contaminated with 20% zinc or so, high enough that it's unquestionably bad for casting bullets. Then take the contaminated batch and heat it to 1800 or so under a blanket of graphite on the surface to prevent excessive oxidation of the lead.
If the zinc does boil, the zinc gas will probably combust somewhere in the graphite blanket, filling it with zinc oxide powder, and producing very little toxic fumes, compared to the sulfur slag method which produces copious sulfur dioxide, zinc sulfate (toxic to fish), and hydrogen gas.
What do you all think? Worth testing?