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View Full Version : Mystery alloy - possible to identify?



cmk
09-20-2018, 03:31 PM
I've read stickies, and tried a bit of googling, but there are just too many possible varieties, so I thought it prudent to ask.

Before even getting ANY casting gear, I came across a guy who was parting with some lead/alloys at a reasonable price. It all came in form rather large bricks 30-50 lbs each. As I have now started smelting it into smaller ingots, I have made some interesting discoveries regarding one of the alloys.

It melts a really(?) low temp, fully liquid at 350F / 175C, but below that it was getting slushy. Not much oxidation forming on the surface (but then again, it was not running particularly hot, say 450-480F). Poured some ingots and as they were cooling/solidifying, it seemed like it was it was actually two (or more) distinct metals, i.e. like mercury floating 'through' the otherwise solidified ingot when tilting the mold back and forth. Don't really know how to describe it better than that. And it takes a long time to solidify fully. A couple of minutes at least.

Once fully solid on the surface I turned the mold upside down, and it dropped out quite nicely, but leaving slight smears in the mold as it was probably quite close to the melting point for one of the metals. Came out sort of shiny on the surface, but quickly (1 minute) turned into a frosty white colour,

Interesting thing is that the original brick looked and felt more like pure lead, i.e. dull gray and easy to dent with a light hammer blow, but in its new ingot shape it is slightly a different story It seems a little harder, and when water quenched, it seems a little harder still. I have no equipment to do any real BHN test. It will scratch with a nail (carpentry, not finger), but it's possible to polish away the 'frosting' with a nail (finger variety). That area then stays shiny for at least a week (maybe forever - time would tell).

Is there any way to figure out what it is? Or could anyone come up with a guess? Or some other type of test that could be done to determine its contents? Since I don't yet have a bullet mold, I cannot accurately measure shrinkage compared to a pure lead bullet or something like that. The one remaining brick has a density of 11.89 if that can help determining things.

EDIT: I realize now that such a density would higher than pure lead, and there was probably something wrong with my calculation/measurement. Unless there is tungsten or uranium in the mix. But that would not explain the low melt temp. /EDIT

I contacted the seller and he did not really know either (he got it from work, but I don't quite recall what he said he worked with), but he admitted it was a bit hard to cast with, and he had himself mixed it with ~30% pure lead for more reliable results.

Anyone up for a guess?

Thanks in advance.
cmk

* Edited for factual errors

rancher1913
09-20-2018, 03:37 PM
contact bne on here.

cmk
09-21-2018, 11:14 AM
Thanks, sent a PM.

modified5
09-22-2018, 10:57 AM
It will be interesting to see what this comes out as.

Lloyd Smale
09-23-2018, 07:11 AM
don't know what you have there but even tin takes a bit over 400 degrees F to melt.

rmark
09-23-2018, 03:17 PM
Could your thermometer be off? It might read 350 but the temperature is actually higher.

Jeffrey
09-23-2018, 04:11 PM
I second having BNE take a look at it if you cannot get it to a XrF holder in your area. BNE did some good work for me. There are such things as "fusible metals": cerrosafe is one of them, that melt at fairly low temperatures. https://www.rotometals.com/low-melt-fusible-alloys/

cmk
09-23-2018, 04:15 PM
I believe the thermometer to be reasonably accurate. It is not really intended for lead pots, but rather for measuring the heat of smoke in chimneys. Ranges from 50C (122F) up to 500C (932F)

Did test it with boiling water and it was correct within a few %.

I melted down another 'brick' from a totally different source yesterday, and it took a lot longer, so I believe that the 'low-temp' aspect of the mystery-alloy is indeed true. Maybe not to the exact degree, but near that.

John Boy
09-23-2018, 09:08 PM
Check the temperature on the alloy chart where Sn & Sb cross at 40% of the second metal ...
https://www.engineeringtoolbox.com/melting-points-mixtures-metals-d_1269.html

If the composition is correct, with 30-50 lb bricks - you just won the lottery

Good Cheer
09-23-2018, 10:36 PM
If you break an ingot before it fully solidifies does it look something like this?
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This was some really soft stuff, moderately difficult to get good boolits molded. Shot OK.

cmk
09-24-2018, 10:04 AM
Check the temperature on the alloy chart where Sn & Sb cross at 40% of the second metal ...
https://www.engineeringtoolbox.com/melting-points-mixtures-metals-d_1269.html

If the composition is correct, with 30-50 lb bricks - you just won the lottery


Yeah I've seen that chart before, and the only things that make sense from a temperature perspective is either 65% tin 35%lead, OR something 40% bismuth, 60% lead.

Neither of those would really make me super-happy. I didn't mention this before, but I am aiming to cast for rifle speeds, so I guess I'll be needing something harder than just a tin/lead alloy.

Well, anyway, samples are en route for analysis.

cmk
09-24-2018, 10:11 AM
If you break an ingot before it fully solidifies does it look something like this?
227676
This was some really soft stuff, moderately difficult to get good boolits molded. Shot OK.

Nice picture - but I'll have to postpone further ingot-making for a later date, at least for a couple of weeks, and by that time I might already have the answer.

thanks,

kevin c
09-24-2018, 05:08 PM
BNE will tell you for sure.

If it's high tin, even if you can't use it yourself, you could sell/trade some or all of it for what you need, and would end up getting back a lot more than you off load.

cmk
09-24-2018, 06:06 PM
BNE will tell you for sure.

If it's high tin, even if you can't use it yourself, you could sell/trade some or all of it for what you need, and would end up getting back a lot more than you off load.

Maybe. But tin is not so hard to come by, at least not in the form of pewter. Which should be high enough in tin to treat it as pure AFAIK. Isn't it normally 85+ % tin, with some lead and/or antimony thrown into the mix? And from my understanding even those who use a tin-rich mix in their alloys, e.g 1/16, would be able to cover a lot of their needs by visiting the occasional yard sale.

I thought antimony was a lot harder to find since the decline in COWW. But as I mentioned earlier, bullet casting is rather new to me - to say the least.

kevin c
09-25-2018, 03:24 AM
There do seem to be regional differences in availability for the metals we want for casting. I had not picked up on the fact that you are in Europe, where pewter might be more common than in my part of the USA. Type metal, a source of antimony, is becoming scarce like lead wheel weights, but I buy mine from a local metals foundry (Rotometals).

Traffer
09-25-2018, 03:42 AM
Here are some low melt alloys that may give you some idea of what metals are in your mix:
https://www.canfieldmetals.com/low_melt_alloys.htm

cmk
10-10-2018, 04:42 PM
And the verdict is back from BNE:

Pb = 74.7%
Sb = 0.8%
Sn = 24.5%

So in short, I probably have a faulty thermometer, as this alloy should be melting at a much higher temp than it indicated. And I don't think it is useful in its current state.

Hmm, I'd really like to get my hands on some Sb-rich lead....

Petander
10-14-2018, 07:43 AM
Now that's lots of tin. Good for mixing with other alloys.


http://www.lasc.us/CastBulletAlloy.htm

cmk
10-14-2018, 07:34 PM
Yep, it sure is. Too much for my taste :-)

Right now I have about 60-80 lbs of the stuff, and I figure that I only need something like 2% Sn in my final alloys. Oh well, I guess this is a bit of a first-world problem :-)

kevin c
10-15-2018, 12:52 AM
Ah, there are many here who wish to have your problem ;^D

shafer44
10-15-2018, 06:40 PM
be nice to have a bunch of that for the tin

cmk
10-21-2018, 04:38 PM
Hm, yes it is nice to have, but I don't really see the need for copious amounts of tin. One only needs like 1-2%, right, so what I have (including some pewter) would be enough for a ton of lead. I don't see myself shooting that much in my remaining years. What I would like is a good source of antimony. And COWW are hard to come by these days.

Petander
11-01-2018, 06:37 AM
Hm, yes it is nice to have, but I don't really see the need for copious amounts of tin. One only needs like 1-2%, right, so what I have (including some pewter) would be enough for a ton of lead. I don't see myself shooting that much in my remaining years. What I would like is a good source of antimony. And COWW are hard to come by these days.

A ton is not that much when you shoot regularly. I'm recycling my boolits back to melt because I only have a ton of alloy.

Just got my Hard Alloy XRF:

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