After firing a round, measure the inside diameter of the mouth on the fired case.
If your bullet diameter is not (at least) as large as that dimension, it can probably be called 'undersized'.
Most Pedersoli chambers will accept a cartridge with a .460" bullet seated in it. Shooting the fattest bullet that will chamber smoothly is the 'best idea' in my book.
However, when using a 'soft' bullet of 10 BHN or less, and propelling it with black powder, the bullet will bump up to seal off gases if it is even only 'close to' the groove diameter of the barrel.
If there is any doubt that the bullet is expanding fast enough, seat it so that it is in contact with the rifling lands.
That will retard it's movement long enough to get obturation.
In your quest to discover the cause of your leading, there is a project that you can use to fill time between target matches.
Using Cerro-safe to make a cast, or soft lead to make an impact impression, create a model of the interior of your chamber ... a chamber cast.
(discussions of those processes are prolific on this site)
This may (probably will) show your chamber to be notably longer than the nominal 2.1 inches expected in a 45/70 chamber.
If such is the case, compare the length of a fired case with the actual depth of the chamber.
Any gap between the case mouth and the chamber end can act as a trap for lead that gets peeled off of a bullet as it leaves the case.
In this situation, peering through your barrel (as suggested earlier) may show leading in the front of your chamber which 'smears' on out through the leade and into the bore.
If you are afflicted with 'short brass', there are two remedies for large gaps.
Stretch the cases you have now, or buy 45/90 brass and trim it back to the dimension in your chamber cast.
If the gap is less than 25 thousandths, leaving a grease groove (or half of a grease groove) exposed right at the mouth of the case might tame the beast.
CM