Hi Ed,
I tend to agree with you about the frictional affect of black powder, but will add that case splitting or separation is definitely possible in modern high-power smokeless ammo in a SAAMI spec'd chamber. I ran into it in a Rem. 700 in .30-06 and, after verifying the chamber specs, conducted an experiment to identify the cause. It turned out that, although the headspace was quite small (only 0.002"), after full-length resizing and firing the case 12 to 13 times, the accumulated affect resulted in the case splitting in front of the thick section ahead of the rim. In this situation, slightly lubricating the chamber would have reduced the possibility of splitting since it would have allowed most or all of the case to move back slightly, not only the rim. Of course it would also increase pressure on the bolt.
Wayne