Don't think the muffin pans are tin coated, mostly Al. coated steel. Usually the problem is the contraction of the steel when cooling - holds on to the ingot tight. turn over on concrete when lead is solid but not cold and they usually drop right out, May need to 'drop' the pan a couple times to get the difficult ones out. As you are smelting, temp of lead is higher than casting temp, steel expands, then contracts when cooling. I don't fill to the top and most are right at 2#.
Leather work gloves are great for casting, along with long sleeve cotton shirt, ball cap - you choice of shield or glasses. Even casting can create lots of little 'spatters' that will not be fun. Lee bottom dripper is notorious.