You will find that Smokes powder makes the whole process easier and appealing to the eye as well. I have found that the Lee push through die metal is pretty soft, if you have a proven method of lapping by hand, to open them up. (Buckshot just got sick after hearing that) If you are having to pound a .432 through the cylinder throats, stop now! You shouldn't have to force a boolit through the throats, just a push by hand. That is probably where your powder coat is coming off. When you get your boolits to fit the throat and they are at least .001 over the barrel diameter, you will be on the right track. Powder coating or lubing are both fine, but fit is king. If you will order some pin gages from Meyer Gage, you will know exactly what you have. They sell pins individually for a couple of $ and they are invaluable to us wheel gun junkies. For the 44, I ordered .427 through .434. If you become fully addicted to this hobby the NOE push through sizer is the way to go. Welcome to the site, there are a lot of great people here with good advice and more than willing to help.