Vaseline in the base VERY bad idea.
Where to start.......
First off, for anything resembling accuracy, the minies will have to be dead soft pure lead AND sized to within .001-2 of bore. Second, don't get hung up on the charge weight. Most minies shoot very well with about 75% of listed service charge weight and NO pyrodex, just the Holy Black. Third, lube is critical. Try using a 50/50 crisco/beeswax for lube. Start out with NOTHING in the base. Observe accuracy and fouling. If fouling is building in the chamber area with each shot, try adding a TINY bit of crisco to the base, meaning a spot smaller than a pea wiped in with your finger. Fourth, caps, CCI Reenactor caps are designed for blanks, good luck getting any accuracy out of them. Go with RWS or Schutzen.
In case you're wondering about what kind of accuracy can be gotten from these Civil War guns, I have 2 Colt Contract Springfields that will both dump 10 shots into one big hole at 50yds and a Parker Hale Enfield that will do it as well. I also have an Enfield musketoon that can do it. It took a while of experimenting to find the right combination but it is possible and while the Colts shoot the same load, it's different for the Enfields, not much but different.
If you're really serious about learning how to shoot the Civil War guns well, to over to the North South Skirmish Association board for more info. We're a competition shooting org that shoots only Civil War weapons, up to and including artillery (yes cannons), for score. I don't think you'll find a more concentrated place with knowledge on how to shoot these guns anywhere on the net. I've read other boards with folks spouting off about these guns but most of it is tripe gotten second hand from a cousin's friend or something. There are a couple on this board in the NSSA and if they offer advice and mention they're NSSA, you'd do well to listen.
n-ssa.net