OK: so everyone is on the same page here the "Bore Diameter" is the size of the hole that gets drilled and reamed into the barrel prior to the rifling operation. This dimension is from the top of the land to the top of the land across from it after the rifling is done.
Typically Rifling Grooves are .004-.005 deep. Groove Diameter measured is from the bottom of the groove to the bottom of the groove across from it. This only works right with even numbers of lands a grooves. 3 or 5 grooves is a PITB.
If your bore Dia. on that gun is .450 then the groove diameter should be around .458. Which sounds kind of big to me.
The cylinder throats on a revolver are at the front of the cylinder and are ideally .001 larger than the groove dia. of the barrel.
The boolit would be .000 to.001 larger than the throat. This insures a good seal between the bullet and the throat as it transitions from the cylinder to the forcing cone of the barrel and in turn a good seal of the rifling in the barrel which would prevent blow by of gases and transference of lead to the barrel.
Obviously the best way to ascertain these measurements accurately is by slugging both the Cylinder Throats and the Barrel as it is difficult to get good repeatable reading with Calipers.
Then by using the relationships above you can figure out exactly what you need in the way of a boolit mould.
Hope this helps your understanding of this subject..
Randy