I positively do not like the idea of a pinned breechblock. It would be much better if you could find someone to thread the barrel for you on a large lathe... and I don't mean a little better, but much.
In my view if the barrel can't be threaded this gun can't be built. Buf you feel you must go the pinned breechblock route, look for a taper pin reamer and taper pins. Like nearly everything else you will find them on eBay, and dimensions under "Machine tapers" on Wikipedia. I would also epoxy the block to barrel joint - not to add strength, because I don't think it would, after repeated shocks, expansions and contractions. But it would keep fouling out of the joint.