Borderguy - most throat erosion is due to hot gas & burning powder particles at high velocity. 303guy had some pics of boolit bases dented by burning 4895. The Dupont site has a lot of plastic/TiO2 data if someone has a company address that can register and make data available to us? Last time I read the TiO2 content in white paint, it was < 10%. Oh, mohr hardness of annealed copper is 7, most TiO2 is 6. It is also used in suntan lotion, makeup. Probably less hard than fish scales used in makeup. Yes, if you shoot a $2K barrel you might be concerned. But so would guilding metal used in jackets.
It's NOT abrasive enough (HF PC) to remove even minor leading in the barrel. Visible lead in my 40 wasn't removed after 200 rnds PCd. IMHO, until proved otherwise - not a problem.
The yellow has lead chromate coloring in it, a yellow pigment called 'middle chrome'. Navy used it for years as an aluminum corrosion protection. It is slightly toxic. Kind of like red lead. Both red & yellow chrome have mohr hardness of 3. Not a problem.