Acids do little for "cleaning" cases but acids do react with oxidation (tarnish) on brass surfaces and then the tarnish can be wiped off easily. Most any acid will do the job. I prefer the mild acidic acid (3-5%) in common white vinegar because it's cheep and very easy to find.
All chemical reactions work faster when heated but heat doesn't make it work any better. I soak my (occasional) tarnished cases in vinegar over night at room temperature, flush, dry and tumble normally.