The "multiple hit" theory on 12 gauge shotshells is valid only if the buckshot penetrate adequately.....and small buckshot do not. This has been thoroughly tested; I would be glad to provide links to those interested in the topic.
To some extent filling the buck load with smaller shot like F's is wasting space in the shell rather than optimizing it, as the small buckshot sizes cannot be depended upon to penetrate reliably in all instances, even at HD ranges.
Note that F buck does not reliably come anywhere near the accepted "minimum" in penetration in testing.
If a better buckshot load is wanted, rather than alternating small buck with large, simply fill it with number 1 buck. This is said to always penetrate adequately, and there are more of them in a similar space than 00 buck. All the buckshot in the shell are effective, not just some of them.
For a one ounce load, Herco isn't the best choice and spends about 10 grains more powder per shot than is necessary. Better are the trap load type powders.....Red Dot, 700X, Clays. Load under 8 00 buck or 9 0 buck for one ounce practice loads in a WAA12 (white) 1 1/8 ounce wad or its equivalent.