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View Full Version : Alloy Ive read about and the benifits



country gent
03-21-2017, 09:41 PM
Ive read several times of silver being added to lead for alloies for bullets in old accounts the only ratio Ive seen listed in these accounts was a silver dime to 20 lbs lead in a old account. I believe that silver acts as tin in an alloy making it flow and fill out better. My question is what other benefits would there possibly be? any detriments? at the above rate 1 ounce or so would do 100 lbs of lead. Thank you for your help here.

Morgan61
03-21-2017, 09:56 PM
With a melting point of 1763 degrees, how would you get the silver mixed in?

runfiverun
03-21-2017, 10:04 PM
stirring would do it.
antimony melts at 1600 or so but it stirs in just fine.

you are correct about silver adding both a flow ability and a hardness to the lead alloy.
it works somewhere in between copper and Tin.

Dusty Bannister
03-21-2017, 10:31 PM
Thanks R5R, I have been wondering if there was any value to silver as a hardener. I have some solder with a few percent silver but did not think that would add much to the hardness. Especially if only adding a few percent of the solder equal to 2-3% tin.

centershot
03-22-2017, 07:09 AM
Soooo.......if I add 2 or three American quarter dollars to a 20# pot of alloy and stir, stir, stir, I would be adding trace amounts of silver and copper to the melt, yes? If that pot contained Lyman # 2, what would the addition of copper and silver do for me? I'm thinking rifle applications here.

CastingFool
03-22-2017, 07:58 AM
Centershot, the gov't stopped minting silver quarters in 1965, although they did have a special run in 1976 for the bicentennial.

GhostHawk
03-22-2017, 08:13 AM
I suspect even one of the new sandwich quarters being more copper than silver would still help.

I have a pretty good sized bag of pre 64 dimes. I can afford to throw a dime in a 10 lb batch of alloy. See how it behaves.

ioon44
03-22-2017, 08:19 AM
Coin silver is 90% silver and 10% copper, I have a small piece of 98% silver I might try to mix it in to a 20 lb pot to see if it would actually mix in.

Pb Burner
03-22-2017, 08:23 AM
Wouldn't you have to melt the silver dime, then add molten silver into the molten lead while stirring? I wouldn't think the dime would melt at all at normal lead casting temps.

Green Frog
03-22-2017, 08:31 AM
Tradition has it that the buffalo hunters would throw a dime (which WAS mostly silver back then) into their pot of otherwise about pure lead as it melted over their campfire. I can neither confirm nor refute this, but it IS the story I've been told. Has anybody else heard this?

Froggie

PS Of course the Lone Ranger had his bullets cast in pure silver, but according to the old story on TV he had an old miner he had rescued doing that for him... must be true, I saw it on the TV!

Dusty Bannister
03-22-2017, 09:03 AM
The silver does not melt nor does the antimony, at normal casting temps. It will dissolve over time. This requires stirring. I have some of the high tin content solder that also contains some silver and copper so the melting is already done. I just need to blend in what I want to add with the usual melt. Sometimes those silver dimes are worth a lot more than face value. Think before you destroy.

mdi
03-22-2017, 12:04 PM
Well, I don't doubt any of the posters so far, as I'm not a metallurgist, but it isn't logical. If one metal melts at 1,000 degrees higher than another metal, how will the high melting point metal "stir into" the low melting point metal? Will it chemically dissolve? Without powderizing the silver how could it possibly alloy with lead if it does not melt? Seems like you'd just get a hot dime...

fredj338
03-22-2017, 03:22 PM
Any silver in an alloy, like Oregon Trail, is gonna be trace at best. As noted, too hard to get it to blend with lead & costly for little to no gain, unless you are hunting werewolves.
Drop a chunk of antimony into a 700deg lead pot & stir it, see if it ever actually melts.

country gent
03-22-2017, 03:47 PM
Lymans cast bullet manual list silver as an alloy to lead at a low percentage ( sounds like a little goes a long ways here). A small amount wouldn't be hard to melt with a propane torch in the ladle and add in to the molten metal while fluxing. In a hot ladle it shouldn't take long for it to melt while the wood chips are charring then add the silver and paraffin and stir good. I'm curious here and may give it a try at 1 ounce to 100lbs rate. Ive heard the read the accounts of the silver dime added to pure lead ( actually had an old timer tell me to do it when I started and was having problems getting good fill out) it was a dime to a 20 lb pot. Ive read about from accounts of some of the top shutzen shooters. so 5 dimes to 100lbs. I'm not sure theres any silver in the newer coins now copper and nickel now I think.

OuchHot!
03-22-2017, 04:01 PM
You do not have to get the silver molten to get it into a solution that has a high solubility for it. The enthalpy of solution and the entropy gain drives the dissolution of the silver. It is perfectly logical.

HangFireW8
03-22-2017, 04:08 PM
Grinding up the silver hastens the process... More surface area.

-HF

308Jeff
03-22-2017, 04:11 PM
You do not have to get the silver molten to get it into a solution that has a high solubility for it. The enthalpy of solution and the entropy gain drives the dissolution of the silver. It is perfectly logical.

Learn something new on here, every single day. I love this place.

z28z34man
03-22-2017, 06:52 PM
There is absolutely no silver in modern US circulated coinage. It is copper and nickel bonded together under extreme pressure.

BNE
03-22-2017, 08:54 PM
Think of alloying as dissolving. (Similar, for explanatory purposes.)

Table sugar melts at 295F. Your coffee is something less than 212F, yet sugar will readily dissolve or "alloy" with your coffee.

The Silver / Lead eutectic (Lowest melting mixture.) is 2.27%Ag and 97.73%Pb. This mixture melts at 578.7F

SO if you have a pot of molten lead, Silver will dissolve or alloy with it.


Silver acts to toughen the lead. It would work better than Tin in this regard.....I think. I hope to study this in more detail someday.

snowtigger
03-25-2017, 11:54 AM
I made some 6% silver boolits. I got tired of reading all the reasons it wouldn't work, so I dropped a >999 fine silver ingot into a pot at full temp (about 1100 degrees). Actually, I seem to remember it was 1070, but it was all the pot had to give.
After a while I noticed the corners were beginning to round off, so i waited and finally the ingot disappeared. I don't remember the exact amount, but I do remember it figured out to be 6%.
I cast (casted?) 100 of them. They sure were purty. I tried one of them in the really scientific method ( I put them on an anvil and hit them with a 3lb hammer). They deformed really well without any obvious signs of fracturing. The rest , I diluted to 1% and made some more. They also withstood the hammer test. The 6% models shine up really well and look real nice in a gun belt.
PS: I am now ready for werewolves.
I don't know why I did this. I just always wanted some "Lone Ranger Bullets". If I remember right, they cast well somewhere below 800 degrees. Hope this helps...

dondiego
03-25-2017, 12:31 PM
If anyone wants to try it, any coin shop has US "junk" 90% silver dimes made before 1965 for sale at around $2.00 a piece. They will also have 99.99% pure silver ingots for sale too at around $20 each ounce. I have been a numismatist for over 52 years.

JonB_in_Glencoe
03-25-2017, 12:45 PM
Centershot, the gov't stopped minting silver quarters in 1965, although they did have a special run in 1976 for the bicentennial.
I believe the '76 coins with Ag content was just the proof sets, not the coins for circulation, and those proof set coins only contained 40% Ag...just like the '65 through '69 half dollars.

Last Sept at the gunshow, I sold my last 3 coin '76 proof set.

45-70 Chevroner
03-25-2017, 02:57 PM
With a melting point of 1763 degrees, how would you get the silver mixed in?

That was my exact thought.

Lloyd Smale
03-26-2017, 07:34 AM
sell your silver and buy some lineotype

Morgan61
03-26-2017, 08:22 AM
That gets me thinking. I've got some real old silverware that's I found all bent up and not worth anything except for the silver content. Maybe I'll chop it up & toss it in the melting pot.
Anyone know how to tell if they're pure silver?

JonB_in_Glencoe
03-26-2017, 09:36 AM
it's usually stamped "sterling".
btw, there's lots of silver plate out there, scratch it deeply, those are usually brass or copper underneath.

scottfire1957
03-26-2017, 06:18 PM
Adding silver seems to be an expensive way to make boolits as compared to pewter.

I would sell the silver to buy other components, if priced appropriately. Otherwise, I would keep the silver. COWWs need little or nothing to work well. If you need more hardness, linotype is available cheaper than Ag. 15-20 bucks an oz for Ag, a few dollars a lb for pewter or lino. Ag is not cost effective. IMHO.

facetious
03-26-2017, 08:01 PM
I don't think Oregon Trail adds silver to the lead. I read that it is in there becouse the lead is a byproduct of silver mining. The silver that is left in the lead is the stuff that would cost more to get out then it is worth. It's addvertising value is worth more then the silver.

scottfire1957
03-26-2017, 10:36 PM
Ive read several times of silver being added to lead for alloies for bullets in old accounts the only ratio Ive seen listed in these accounts was a silver dime to 20 lbs lead in a old account. I believe that silver acts as tin in an alloy making it flow and fill out better. My question is what other benefits would there possibly be? any detriments? at the above rate 1 ounce or so would do 100 lbs of lead. Thank you for your help here.

Then again, if you have a silver dime, and you have read such, toss it in! YOU tell us the results and comparisons of 1 (one) silver dime in your alloy. One dime in twenty pounds of alloy?

dondiego
03-27-2017, 04:06 PM
That gets me thinking. I've got some real old silverware that's I found all bent up and not worth anything except for the silver content. Maybe I'll chop it up & toss it in the melting pot.
Anyone know how to tell if they're pure silver?

Your sterling silverware won't be "pure". Sterling is 92.5% silver and 7.5% copper. Very similar to our US silver coinage.

JohnH
03-28-2017, 06:35 PM
It is surprising to me that no one has spoken of using silver solder for this. You can get it at a plumbing supply, prolly even the home despot or lowes (but they always seem high to me...) I considered doing this at one point but in reality, COWW do all I need done. If I want to go faster than circa 2000 fps I use commercially made jacketed bullets. Life's too short for drama and exercises in futility.

starmac
03-29-2017, 12:59 AM
I made some 6% silver boolits. I got tired of reading all the reasons it wouldn't work, so I dropped a >999 fine silver ingot into a pot at full temp (about 1100 degrees). Actually, I seem to remember it was 1070, but it was all the pot had to give.
After a while I noticed the corners were beginning to round off, so i waited and finally the ingot disappeared. I don't remember the exact amount, but I do remember it figured out to be 6%.
I cast (casted?) 100 of them. They sure were purty. I tried one of them in the really scientific method ( I put them on an anvil and hit them with a 3lb hammer). They deformed really well without any obvious signs of fracturing. The rest , I diluted to 1% and made some more. They also withstood the hammer test. The 6% models shine up really well and look real nice in a gun belt.
PS: I am now ready for werewolves.
I don't know why I did this. I just always wanted some "Lone Ranger Bullets". If I remember right, they cast well somewhere below 800 degrees. Hope this helps...

Blame it on the long winter nights.
I have been seeing wolves lately, but they are the regular old wheelweight type. lol

dondiego
03-29-2017, 12:02 PM
I thought of the silver solder too but the test was whether silver would dissolve in a pot of lead and if so, what is the alloy like? I am hoping someone here will perform the test........

.22-10-45
03-29-2017, 02:53 PM
I too read where the old timers would toss a silver dime in a 20# pot of pure lead. Several years ago, I did just that. I bought some old well worn circa 1940 dimes & turned up the heat on my Lyman Mag Dipper pot to max. Alloy was 20-1 pure lead-tin. Dime was placed in Lyman ladel 1/2 filled with 20-1 alloy and covered with flux. Propane torch used to melt silver & melt carefully stirred with more flux added while still in dipper. pot was constantly stirred with dipper & flux added to melt. Bullets cast in Lyman 375248 were shiney..but not noticably any harder. 100yd. groups from a .38-55 Win. High-Wall were the same as with regular lead-tin alloy. They did seem to hold their luster longer.

Tom W.
03-29-2017, 03:20 PM
Me! Me! I tried melting silver solder in my Lee lead pot with the thermostat wide open and it just sat there and floated on top. These were rather small pieces that I had. They never did melt, stirred or not. I suppose I needed a oxycetelene torch to melt them.

NoAngel
03-29-2017, 03:29 PM
Sodium Chloride MELTS at 1,474 degrees but will readily DISSOLVE in hot water.
Aluminum melts at 1,221 degrees but will readily dissolve in a pot of molten zinc....That's how you get pot metal.

308Jeff
03-29-2017, 04:02 PM
Then again, if you have a silver dime, and you have read such, toss it in! YOU tell us the results and comparisons of 1 (one) silver dime in your alloy. One dime in twenty pounds of alloy?

He must resolve to dissolve.

USSR
03-29-2017, 05:21 PM
I'd add my 2 cents, but this thread is dumb enough already.

Don

JohnH
03-29-2017, 09:19 PM
I'd add my 2 cents, but this thread is dumb enough already.

Don That's copper [smilie=1: Just sayin' :wink:

z28z34man
03-30-2017, 05:41 AM
That's copper [smilie=1: Just sayin' :wink:

Nope a modern penny is made of zinc

44man
03-30-2017, 02:08 PM
Any silver in an alloy, like Oregon Trail, is gonna be trace at best. As noted, too hard to get it to blend with lead & costly for little to no gain, unless you are hunting werewolves.
Drop a chunk of antimony into a 700deg lead pot & stir it, see if it ever actually melts.

Actually I alloy with pure antimony at 600° with the proper flux.